Late-Transition-Metal Complexes as Tunable Lewis Bases

被引：62

作者：

Bauer, Juergen ^{[1
]}

Braunschweig, Holger ^{[1
]}

Brenner, Peter ^{[1
]}

Kraft, Katharina ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Schwab, Katrin ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 39期

关键词：

carbenes; density functional calculations; Lewis acids; Lewis bases; platinum; OXIDATIVE-ADDITION-REACTIONS; X-RAY-STRUCTURE; DATIVE BONDS; PALLADIUM(0) COMPLEXES; MOLECULAR-STRUCTURE; BORYLENE COMPLEXES; BLOCK METALS; BU-T; PLATINUM; LIGANDS;

D O I：

10.1002/chem.201001228

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses of the first heteroleptic N-heterocyclic carbene (NHC)-phosphane platinum(0) complexes and formation of the corresponding Lewis acid base adducts with aluminum chloride is reported. The influence of N-heterocyclic carbenes on tuning the Lewis basic properties of the metal complexes was judged from spectroscopic, structural, and computational data. Conclusive experimental evidence for the enhanced Lewis basicity of NHC-containing complexes was provided by a transfer reaction.

引用

页码：11985 / 11992

页数：8

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