Ionic liquid as a green catalytic reaction medium for esterifications

被引：119

作者：

Deng, YQ ^{[1
]}

Shi, F ^{[1
]}

Beng, JJ ^{[1
]}

Qiao, K ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2001年 / 165卷 / 1-2期

关键词：

ionic liquid; esterification; catalyst;

D O I：

10.1016/S1381-1169(00)00422-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Esterifications of alcohols with carboxylic acids in the room temperature ionic liquid 1-butylpyridinium chloride-aluminium(III) chloride as green reaction medium in catalytic quantities have been investigated. Excellent conversion and selectivities were achieved, and the most of resultant esters could be easily recovered due to immiscibility with the ionic liquid. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：33 / 36

页数：4

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共 13 条

[1] Palladium catalysed allylation reactions in ionic liquids [J].

Chen, WP ;

Xu, LJ ;

Chatterton, C ;

Xiao, JL .

CHEMICAL COMMUNICATIONS, 1999, (13) :1247-1248

[2] Selective catalytic hydrodimerization of 1,3-butadiene by palladium compounds dissolved in ionic liquids [J].

Dullius, JEL ;

Suarez, PAZ ;

Einloft, S ;

de Souza, RF ;

Dupont, J ;

Fischer, J ;

De Cian, A .

ORGANOMETALLICS, 1998, 17 (05) :815-819

[3] Organometallic synthesis in ambient temperature chloroaluminate(III) ionic liquids. Ligand exchange reactions of ferrocene [J].

Dyson, PJ ;

Grossel, MC ;

Srinivasan, N ;

Vine, T ;

Welton, T ;

Williams, DJ ;

White, AJP ;

Zigras, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (19) :3465-3469

[4] Regioselective alkylation in ionic liquids [J].

Earle, MJ ;

McCormac, PB ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 1998, (20) :2245-2246

[5] Diels-Alder reactions in room-temperature ionic liquids [J].

Fischer, T ;

Sethi, A ;

Welton, T ;

Woolf, J .

TETRAHEDRON LETTERS, 1999, 40 (04) :793-796

[6] Heck reaction catalyzed by phospha-palladacycles in non-aqueous ionic liquids [J].

Herrmann, WA ;

Böhm, VPW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 572 (01) :141-145

[7] SOLID CATALYSTS TREATED WITH ANIONS .13. SYNTHESIS OF ESTERS FROM TEREPHTHALIC AND PHTHALIC ACIDS WITH N-OCTYL AND 2-ETHYLHEXYL ALCOHOL, ACRYLIC-ACID WITH ETHANOL AND SALICYLIC-ACID WITH METHANOL CATALYZED BY SOLID SUPERACID [J].

HINO, M ;

ARATA, K .

APPLIED CATALYSIS, 1985, 18 (02) :401-404

[8] Room temperature ionic liquids as novel media for 'clean' liquid-liquid extraction [J].

Huddleston, JG ;

Willauer, HD ;

Swatloski, RP ;

Visser, AE ;

Rogers, RD .

CHEMICAL COMMUNICATIONS, 1998, (16) :1765-1766

[9] Clean catalysis with ionic solvents - phosphonium tosylates for hydroformylation [J].

Karodia, N ;

Guise, S ;

Newlands, C ;

Andersen, JA .

CHEMICAL COMMUNICATIONS, 1998, (21) :2341-2342

[10] Comparison of polyvinylbenzene and polyolefin supported sulphonic acid catalysts in the esterification of acetic acid [J].

Mäki-Arvela, P ;

Salmi, T ;

Sundell, M ;

Ekman, K ;

Peltonen, R ;

Lehtonen, J .

APPLIED CATALYSIS A-GENERAL, 1999, 184 (01) :25-32