The Influence of the Acidity of Ionic Liquids on Catalysis

被引:62
作者
Cui, Xinjiang [1 ,2 ]
Zhang, Shiguo [1 ,2 ]
Shi, Feng [1 ]
Zhang, Qinghua [1 ]
Ma, Xiangyuan [1 ]
Lu, Liujin [1 ]
Deng, Youquan [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
anions; acidity; catalysis; cations; ionic liquids; CARBONYL-COMPOUNDS; ACETALIZATION; EFFICIENT;
D O I
10.1002/cssc.201000075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reactions performed in ionic liquids with BF4- as anion progress under strongly acidic conditions. The acidity of some air- and moisture-stable ionic liquids is explored and its effect on catalytic reactions is studied. The function of these ionic liquids in some traditional acid-catalyzed reactions is also tested, and the results merit a reconsideration of their influence on catalytic reactions and use in other applications. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1043 / 1047
页数:5
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