Bisphenol A sensing based on surface molecularly imprinted, ordered mesoporous silica

被引：58

作者：

Wang, Yaqiong ^{[1
]}

Yang, Yuanyuan ^{[1
]}

Xu, Lan ^{[1
]}

Zhang, Jin ^{[1
]}

机构：

[1] Southwest Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Luminescence & Real Time Anal, Chongqing 400715, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2011年 / 56卷 / 05期

关键词：

Surface molecularly imprinted; Ordered mesoporous silica; Carbon paste electrode; Bisphenol A; PHASE MICROEXTRACTION; LIQUID-CHROMATOGRAPHY; SENSOR; POLYMER; MEMBRANES; SIEVES; WATER;

D O I：

10.1016/j.electacta.2010.11.077

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Molecularly imprinted, ordered mesoporous silica was synthesized using bisphenol A (BPA) as the template and 3-aminopropyltriethoxysilane modified with hexagonally structured mesoporous silica (SBA-15) as the carrier. Carbon paste sensors were constructed by mixing the molecularly imprinted, ordered mesoporous silica with graphite powder and paraffin oil, and they were found to detect bisphenol A (BPA) with enhanced selectivity due to their ordered mesoporous structure and their successful molecular imprinting. The linear range for the proposed sensor was 1.000 x 10(-7) mol L-1 to 5.000 x 10(-4) mol L-1, and the detection limit was determined to be 3.222 x 10(-8) mol L-1. Overall, the sensor detected the water samples with satisfactory results. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2105 / 2109

页数：5

共 29 条

[1] Determining leaching of bisphenol A from plastic containers by solid-phase microextraction and gas chromatography-mass spectrometry [J].

Chang, CM ;

Chou, CC ;

Lee, MR .

ANALYTICA CHIMICA ACTA, 2005, 539 (1-2) :41-47

[2] Mechanical stability and porosity analysis of large-pore SBA-15 mesoporous molecular sieves by mercury porosimetry and organics adsorption [J].

Hartmann, M ;

Vinu, A .

LANGMUIR, 2002, 18 (21) :8010-8016

[3] A novel sol-gel-material prepared by a surface imprinting technique for the selective solid-phase extraction of bisphenol A [J].

Jiang, Xiaoman ;

Tian, Wei ;

Zhao, Chuande ;

Zhang, Haixia ;

Liu, Mancang .

TALANTA, 2007, 72 (01) :119-125

[4] Enhancing adsorptive separations by molecularly imprinted polymers: Role of imprinting techniques and system parameters [J].

Joshi, VP ;

Kulkarni, MG ;

Mashelkar, RA .

CHEMICAL ENGINEERING SCIENCE, 2000, 55 (09) :1509-1522

[5] Miniaturized hollow fiber assisted liquid-phase microextraction with in situ derivatization and gas chromatography-mass spectrometry for analysis of bisphenol A in human urine sample [J].

Kawaguchi, Migaku ;

Ito, Rie ;

Okanouchi, Noriya ;

Saito, Koichi ;

Nakazawa, Hiroyuki .

JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2008, 870 (01) :98-102

[6] A Sensitive and reliable quantification method for Bisphenol A based on modified competitive ELISA method [J].

Kim, Andre ;

Li, Chun-Ri ;

Jin, Chun-Feng ;

Lee, Keun Woo ;

Lee, Sang-Hoon ;

Shon, Kwang-Jae ;

Park, Nam Gyu ;

Kim, Dong-Kyoo ;

Kang, Shin-Won ;

Shim, Yoon-Bo ;

Park, Jang-Su .

CHEMOSPHERE, 2007, 68 (07) :1204-1209

[7] A molecularly imprinted polymer on indium tin oxide and silicon [J].

Kindschy, LM ;

Alocilja, EC .

BIOSENSORS & BIOELECTRONICS, 2005, 20 (10) :2163-2167

[8] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

[9] Effects of added organosilanes on the formation and adsorption properties of silicates surface-imprinted with an organophosphonate [J].

Markowitz, MA ;

Deng, G ;

Gaber, BP .

LANGMUIR, 2000, 16 (15) :6148-6155

[10] Development of a sensor prepared by entrapment of MIP particles in electrosynthesised polymer films for electrochemical detection of ephedrine [J].

Mazzotta, E. ;

Picca, R. A. ;

Malitesta, C. ;

Piletsky, S. A. ;

Piletska, E. V. .

BIOSENSORS & BIOELECTRONICS, 2008, 23 (07) :1152-1156

← 1 2 3 →