Microstructure and piezoelectric properties of textured (Na0.84K0. 16)0.5Bi0.5TiO3 lead-free ceramics

Textured (Na,K)(0.5)Bi0.5TiO3 ceramics were fabricated by reactive-templated grain growth in combination with tape casting. The effects of sintering conditions on the grain orientation and the piezoelectric properties of the textured (Na,K)(0.5)Bi0.5TiO3 ceramics were investigated. The results show that the textured ceramics have microstructure with plated-like grains aligning in the direction parallel to the casting plane. The ceramics exhibit {h00} preferred orientation and the degree of orientation is larger than 0.7. The degree of grain orientation increases with the increasing sintering temperature. The textured ceramics show anisotropy dielectric and piezoelectric properties in the directions of parallel and perpendicular to the casting plane. The ceramics in the perpendicular direction exhibit better dielectric and piezoelectric properties than those of the nontextured ceramics with the same composition. The optimized sintering temperature is 1150 degrees C where the maximum d(33) of 134pC/N parallel to casting plane, the maximum k(31) of 0.31, and the maximum Q(m) of 154 in perpendicular direction were obtained. (c) 2007 Elsevier Ltd. All rights reserved.