Synthetic and spectroscopic investigations of N(4)-substituted isatin thiosemicarbazones and their copper(II) complexes

被引：88

作者：

Bain, GA

West, DX

Krejci, J

ValdesMartinez, J

HernandezOrtega, S

Toscano, RA

机构：

[1] ILLINOIS STATE UNIV,DEPT CHEM,NORMAL,IL 61790

[2] UNIV NACL AUTONOMA MEXICO,INST QUIM,COYOACAN,DF,MEXICO

来源：

POLYHEDRON | 1997年 / 16卷 / 05期

关键词：

isatin; thiosemicarbazone; copper(II);

D O I：

10.1016/S0277-5387(96)00323-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of N(4)-substituted thiosemicarbazones of isatin were synthesized and their copper(II) complexes prepared from copper(II) chloride. X-ray crystal structures of two of the thiosemicarbazones, isatin 3-(hexamethylenimylthiosemicarbazone) and isatin 3-(N(4)-ethylthiosemicarbazone), have been solved and are compared with a previously published structure of isatin 3-(N(4)-p-tolythiosemicarbazone). The coordination chemistry of the copper(II) complexes of these and other isatin thiosemicarbazones is reported and discussed. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：855 / 862

页数：8

共 18 条

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