Unexpected variations in the reactivities and selectivities of acyclic and cyclic dehydrodipeptides in Diels-Alder reactions

被引：7

作者：

Burkett, BA

Chai, CLL ^{[1
]}

Hockless, DCR

机构：

[1] Australian Natl Univ, The Faculties, Dept Chem, Canberra, ACT 0200, Australia

[2] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT 0200, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1998年 / 51卷 / 11期

关键词：

D O I：

10.1071/C98116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Diels-Alder reactions of some acyclic and cyclic dehydrodipeptides have been investigated. Our studies show that the reactivities of the dehydrodipeptides are sensitive to the environment of the double bond. In addition, the exo/endo selectivity of the cycloaddition is enhanced in the cyclic as compared to the acyclic systems.

引用

页码：993 / 997

页数：5

共 20 条

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