A new modification of the laves phase CaLi2

被引：22

作者：

Fischer, D ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Max Planck Inst Festkorperforsch, D-70506 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2003年 / 629卷 / 11期

关键词：

lithium; calcium; laves phase; structure elucidation; thermal properties;

D O I：

10.1002/zaac.200300179

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new modification of CaLi2 (beta-CaLi2) was obtained by simultaneous deposition of calcium and lithium on a sapphire substrate. This compound crystallizes cubic in the MgCu2-structure type (Fd (3) over barm, a = 885.6(1) pm, R-p=5.1 %, R-wp=6.6 %, structure analysis with the Rietveld-method) and transforms at 150 degreesC into the well-known hexagonal alpha-CaLi2. The thermal behavior was studied by temperature-dependent X-ray diffraction.

引用

页码：1934 / 1936

页数：3

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