Catalytic carbon-carbon bond activation of sec-alcohols by a rhodium(I) complex

被引：53

作者：

Jun, CH ^{[1
]}

Lee, DY ^{[1
]}

Kim, YH ^{[1
]}

Lee, H ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 13期

关键词：

D O I：

10.1021/om010087c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K2CO3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

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页码：2928 / 2931

页数：4

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