Catalytic carbon-carbon bond activation of sec-alcohols by a rhodium(I) complex

被引：53

作者：

Jun, CH ^{[1
]}

Lee, DY ^{[1
]}

Kim, YH ^{[1
]}

Lee, H ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 13期

关键词：

D O I：

10.1021/om010087c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K2CO3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

引用

页码：2928 / 2931

页数：4

共 56 条

[41] CATALYTIC HYDROGENOLYSIS OF AN ARYL-ARYL CARBON-CARBON BOND WITH A RHODIUM COMPLEX [J].

PERTHUISOT, C ;

JONES, WD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3647-3648

[42]

RUSSELL GA, 1993, SYNLETT, P701

[43]

Rybtchinski B, 1999, ANGEW CHEM INT EDIT, V38, P870, DOI 10.1002/(SICI)1521-3773(19990401)38:7<870::AID-ANIE870>3.0.CO

[44]

2-3

[45] ASYMMETRIC REDUCTION OF CARBON-CARBON DOUBLE-BONDS OF CONJUGATED ENONES WITH FERMENTING BAKERS-YEAST [J].

SAKAI, T ;

MATSUMOTO, S ;

HIDAKA, S ;

IMAJO, N ;

TSUBOI, S ;

UTAKA, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (11) :3473-3475

[46] DIRECT NUCLEOPHILIC 1,4-ACYLATION OF ALPHA-BETA-UNSATURATED KETONES AND ALDEHYDES VIA ACYLCUPRATE REAGENTS [J].

SEYFERTH, D ;

HUI, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (15) :4551-4553

[47] An improved mimetic compound for styrene "living" free radical polymerization. An initiator containing the "penultimate" unit [J].

Skene, WG ;

Scaiano, JC ;

Yap, GPA .

MACROMOLECULES, 2000, 33 (10) :3536-3542

[48] EFFECT OF CHARGE-DISTRIBUTION ON SELECTIVE HYDROGENATION OF CONJUGATED ENONES CATALYZED BY IRIDIUM COMPLEXES [J].

SPOGLIARICH, R ;

FARNETTI, E ;

GRAZIANI, M .

TETRAHEDRON, 1991, 47 (10-11) :1965-1976

[49] DIRECTED CLEAVAGE OF CARBON-CARBON BONDS BY TRANSITION-METALS - THE ALPHA-BONDS OF KETONES [J].

SUGGS, JW ;

JUN, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) :3054-3056

[50] METAL-CATALYZED ALKYL KETONE TO ETHYL KETONE CONVERSIONS IN CHELATING KETONES VIA CARBON CARBON BOND-CLEAVAGE [J].

SUGGS, JW ;

JUN, CH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (02) :92-93

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