Linear trinuclear three-centred metal-metal multiple bonds: Synthesis and crystal structure of [M(3)(dpa)(4)Cl-2] [M=Ru-II or Rh-II, dpa=bis(2-pyridyl)amido anion]

被引：139

作者：

Sheu, JT

Lin, CC

Chao, I

Wang, CC

Peng, SM

机构：

[1] NATL TAIWAN UNIV, DEPT CHEM, TAIPEI 10764, TAIWAN

[2] ACAD SINICA, INST CHEM, TAIPEI 11529, TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 03期

关键词：

D O I：

10.1039/cc9960000315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and X-ray crystal structures of the linear trinuclear metal complexes, [M(3)(II)(dpa)(4)Cl-2] (M = Ru or Rh), with a syn-syn bis(2-pyridyl)amido (dpa) ligand, possessing a short M-M-M three-centred multiple bond [Ru-Ru 2.2537(5) Angstrom; Rh-Rh 2.3920(5) Angstrom] are described.

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页码：315 / 316

页数：2

相关论文

共 21 条

[1] CRYSTAL-STRUCTURE AND ELECTRONIC-PROPERTIES OF TETRAKIS[MU-3-BIS(2-PYRIDYL)AMIDO]DICHLOROTRINICKEL(II) WATER ACETONE (1/0.23/0.5) [J].

ADULDECHA, S ;

HATHAWAY, B .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (04) :993-998

[2] 3-CENTER OXIDATIVE ADDITION - FORMATION, STRUCTURE, AND DISSOCIATION OF (PHCH2NC)12RH3I23+ AND RELATED CATIONS [J].

BALCH, AL ;

OLMSTEAD, MM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (11) :3128-3129

[3] STRUCTURAL STUDIES OF SOME MULTIPLY BONDED DIRUTHENIUM TETRACARBOXYLATE COMPOUNDS [J].

BINO, A ;

COTTON, FA ;

FELTHOUSE, TR .

INORGANIC CHEMISTRY, 1979, 18 (09) :2599-2604

[4] UNIQUE ECLIPSED COFACIAL OLIGOMERIC COMPLEXES OF RHODIUM CONTAINING 3-LAYERED BONDING OF 9,10-PHENANTHROQUINONEDIIMINE [J].

CHERN, SS ;

LEE, GH ;

PENG, SM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (14) :1645-1646

[5] TETRANUCLEAR COMPLEXES AS INTERMEDIATES IN TRANS-ANNULAR OXIDATIVE-ADDITION REACTIONS - STRUCTURE OF THE 1ST TETRAIRIDIUM LINEAR CLUSTER [J].

CIRIANO, MA ;

SEBASTIAN, S ;

ORO, LA ;

TIRIPICCHIO, A ;

CAMELLINI, MT ;

LAHOZ, FJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03) :402-403

[6]

Cotton F.A., 1993, MULTIPLE BONDS METAL

[7] MULTIPLE CHROMIUM(II)-CHROMIUM(II) AND RHODIUM(II)-RHODIUM(II) BONDS [J].

COTTON, FA ;

DEBOER, BG ;

LAPRADE, MD ;

PIPAL, JR ;

UCKO, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (09) :2926-&

[8] DIMOLYBDENUM TETRAACETATE [J].

COTTON, FA ;

MESTER, ZC ;

WEBB, TR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (NOV15) :2768-2770

[9]

COTTON FA, 1988, ADV INORG CHEM, pCH23

[10]

FACKLER JP, 1989, METAL METAL BONDS CL