Linear trinuclear three-centred metal-metal multiple bonds: Synthesis and crystal structure of [M(3)(dpa)(4)Cl-2] [M=Ru-II or Rh-II, dpa=bis(2-pyridyl)amido anion]

被引：139

作者：

Sheu, JT

Lin, CC

Chao, I

Wang, CC

Peng, SM

机构：

[1] NATL TAIWAN UNIV, DEPT CHEM, TAIPEI 10764, TAIWAN

[2] ACAD SINICA, INST CHEM, TAIPEI 11529, TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 03期

关键词：

D O I：

10.1039/cc9960000315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and X-ray crystal structures of the linear trinuclear metal complexes, [M(3)(II)(dpa)(4)Cl-2] (M = Ru or Rh), with a syn-syn bis(2-pyridyl)amido (dpa) ligand, possessing a short M-M-M three-centred multiple bond [Ru-Ru 2.2537(5) Angstrom; Rh-Rh 2.3920(5) Angstrom] are described.

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页码：315 / 316

页数：2

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