Synthesis of oligomers having a pendant dithienosilole unit and their applications to EL device materials

被引：19

作者：

Lee, KH

Ohshita, J

Kimura, K

Kunugi, Y

Kunai, A

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

[2] Hiroshima Univ, Fac Integrated Arts & Sci, Div Sci Mat, Higashihiroshima 7298521, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 02期

关键词：

dithienosilole; electroluminescence; polyethylene; radical polymerization;

D O I：

10.1016/j.jorganchem.2004.09.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oligomers bearing dithienosilole as a pendent were prepared by radical polymerization of the corresponding dithienosilole monomer using AIBN as an initiator. The resulting oligomers exhibited high solubility in common organic solvents and strong photofluorescences (Phi = 0.72-0.76) in THF which are a little higher than that of monomeric dithienosilole DTS(TMS)(2). Applications of the oligomers to EL devices as hole transporting materials were examined and the maximum electroluminance of 2140 cd/m(2) was obtained from a device composed of ITO/oligomer/Alq(3)/Mg-Ag. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：333 / 337

页数：5

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