共 57 条
Room-Temperature Ionic Liquid. A New Medium for Material Production and Analyses under Vacuum Conditions
被引:134
作者:
Kuwabata, Susumu
[1
,2
]
Tsuda, Tetsuya
[1
,3
]
Torimoto, Tsukasa
[2
,4
]
机构:
[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Osaka Univ, Grad Sch Engn, Frontier Res Base Global Young Researchers, Suita, Osaka 5650871, Japan
[4] Nagoya Univ, Dept Crystalline Mat Sci, Grad Sch Engn, Chikusa Ku, Aichi 4648603, Japan
来源:
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
|
2010年
/
1卷
/
21期
基金:
日本科学技术振兴机构;
关键词:
ALLOY NANOPARTICLES;
SPUTTER-DEPOSITION;
GOLD NANOPARTICLES;
REACTION-KINETICS;
PULSE-RADIOLYSIS;
MS ANALYSIS;
IN-VACUO;
MALDI-MS;
ELECTRON;
METAL;
D O I:
10.1021/jz100876m
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
A characteristic of negligible vapor pressure that a room temperature ionic liquid (RTIL) possesses enables us to introduce RTILs in the apparatus requiring vacuum conditions for material production and analyses. This combination creates a path toward development of new techniques under vacuum conditions. As for material production especially metal nanoparticle synthesis, those are magnetron sputtering onto TRILs, plasma reduction in RTILs, physical vapor deposition onto RTILs, and electron beam and g-ray irradiation to RTILs. Interestingly the nanoparticles prepared in RTILs without any stabilizing agent do not aggregate in the RTILs. Also, we can introduce RTILs in analytical instruments requiring vacuum conditions such as X-ray photospectroscopy (XPS), matrix-assisted laser desorption/ionization mass spectroscopy (MALDI, MS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The fact that the RTIL is not charged under irradiation by quantum beams enables us to establish new analytical techniques. Furthermore, homogeneous conditions that are obtainable by dissolving a substance in a RTIL are quite useful for conducting analyses using the instruments described above for example MALDI-MS with high reproducibility.
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页码:3177 / 3188
页数:12
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