The first example of a hetero-tetranuclear [(VO)Gd]2 complex:: synthesis, crystal structure and magnetic properties of [VOLGd(hfa)2CH3OH]2•2CH3OH•2(CH3)2CO

被引：17

作者：

Costes, JP

Shova, S

Clemente Juan, JM

Suet, N

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Moldova State Univ, Dept Chem, Kishinev 2009, Moldova

[3] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain

来源：

DALTON TRANSACTIONS | 2005年 / 17期

关键词：

D O I：

10.1039/b506102d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cyclic tetranuclear [(VO)-O-IV-Gd-III](2) complex with VO and Gd ions alternately arrayed, behaves, from the magnetic point of view, as two independent dinuclear entities each having a S = 4 ground state, as a consequence of an active and ferromagnetic VO-Gd interaction through the double phenoxo bridge and a magnetically inactive VO-Gd interaction through the amide bridge.

引用

页码：2830 / 2832

页数：3

共 25 条

[1] [Anonymous], 2015, Acta Crystallogr., V71, P3
[2] CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS
BENCINI, A
BENELLI, C
CANESCHI, A
CARLIN, RL
DEI, A
GATTESCHI, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8128 - 8136
[3] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals
Benelli, C
Gatteschi, D
[J]. CHEMICAL REVIEWS, 2002, 102 (06) : 2369 - 2387
[4] High-nuclearity magnetic clusters:: Generalized spin Hamiltonian and its use for the calculation of the energy levels, bulk magnetic properties, and inelastic neutron scattering spectra
Borrás-Almenar, JJ
Clemente-Juan, JM
Coronado, E
Tsukerblat, BS
[J]. INORGANIC CHEMISTRY, 1999, 38 (26) : 6081 - 6088
[5] MAGPACK1 a package to calculate the energy levels, bulk magnetic properties, and inelastic neutron scattering spectra of high nuclearity spin clusters
Borrás-Almenar, JJ
Clemente-Juan, JM
Coronado, E
Tsukerblat, BS
[J]. JOURNAL OF COMPUTATIONAL CHEMISTRY, 2001, 22 (09) : 985 - 991
[6] Synthesis, structure, and magnetic properties of tetranuclear cubane-like and chain-like iron(II) complexes based on the N4O pentadentate dinucleating ligand 1,5-bis[(2-pyridylmethyl)amino]pentan-3-ol
Clemente-Juan, JM
Mackiewicz, C
Verelst, M
Dahan, F
Bousseksou, A
Sanakis, Y
Tuchagues, JP
[J]. INORGANIC CHEMISTRY, 2002, 41 (06) : 1478 - 1491
[7] Is ferromagnetism an intrinsic property of the CuII/GdIII couple?: 1.: Structures and magnetic properties of two novel dinuclear complexes with a μ-phenolato-μ-oximato (Cu,Gd) core
Costes, JP
Dahan, F
Dupuis, A
Laurent, JP
[J]. INORGANIC CHEMISTRY, 2000, 39 (02) : 169 - 173
[8] Unprecedented (Cu2Ln)n complexes (Ln = Gd3+, Tb3+):: A new "single chain magnet"
Costes, JP
Clemente-Juan, JM
Dahan, F
Milon, J
[J]. INORGANIC CHEMISTRY, 2004, 43 (26) : 8200 - 8202
[9] Synthesis, structures, and magnetic properties of novel mononuclear, tetranuclear, and 1D chain MnIII complexes involving three related asymmetrical trianionic ligands
Costes, JP
Dahan, F
Donnadieu, B
Douton, MJR
García, MIF
Bousseksou, A
Tuchagues, JP
[J]. INORGANIC CHEMISTRY, 2004, 43 (08) : 2736 - 2744
[10] Costes JP, 2002, CHEM-EUR J, V8, P5430, DOI 10.1002/1521-3765(20021202)8:23<5430::AID-CHEM5430>3.0.CO

← 1 2 3 →