The first example of a hetero-tetranuclear [(VO)Gd]2 complex:: synthesis, crystal structure and magnetic properties of [VOLGd(hfa)2CH3OH]2•2CH3OH•2(CH3)2CO

被引：17

作者：

Costes, JP

Shova, S

Clemente Juan, JM

Suet, N

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Moldova State Univ, Dept Chem, Kishinev 2009, Moldova

[3] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain

来源：

DALTON TRANSACTIONS | 2005年 / 17期

关键词：

D O I：

10.1039/b506102d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cyclic tetranuclear [(VO)-O-IV-Gd-III](2) complex with VO and Gd ions alternately arrayed, behaves, from the magnetic point of view, as two independent dinuclear entities each having a S = 4 ground state, as a consequence of an active and ferromagnetic VO-Gd interaction through the double phenoxo bridge and a magnetically inactive VO-Gd interaction through the amide bridge.

引用

页码：2830 / 2832

页数：3

共 25 条

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