Indium hydride: a novel radical initiator in the reduction of organic halides with tributyltin hydride

被引：54

作者：

Inoue, K ^{[1
]}

Sawada, A ^{[1
]}

Shibata, I ^{[1
]}

Baba, A ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mol Chem, Suita, Osaka 5650871, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 28期

基金：

日本学术振兴会;

关键词：

indium and compounds; transmetallation; catalysis; radicals and radical reactions;

D O I：

10.1016/S0040-4039(01)00816-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dichloroindium hydride (Cl2InH), which was generated in situ by transmetallation between tributyltin hydride and indium trichloride, acted as a novel radical initiator for the reduction of organic halides with tributyltin hydride. The reaction was revealed to proceed through a radical process under non-oxygen conditions at room temperature, and to be applicable to intramolecular radical cyclizations. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：4661 / 4663

页数：3