Carbon-silica composite adsorbent: Characterization and adsorption of light gases

被引：53

作者：

Glover, T. Grant ^{[1
]}

Dunne, Kamini I. ^{[2
]}

Davis, Robert J. ^{[2
]}

LeVan, M. Douglas ^{[1
]}

机构：

[1] Vanderbilt Univ, Dept Chem Engn, Nashville, TN 37235 USA

[2] Univ Virginia, Dept Chem Engn, Charlottesville, VA 22904 USA

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2008年 / 111卷 / 1-3期

关键词：

adsorbent; carbon; carbon-silica composite; furfuryl alcohol; MCM-41; carbogenic molecular sieve;

D O I：

10.1016/j.micromeso.2007.07.012

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A novel carbon-silica composite has been synthesized from MCM-41 and polyfurfuryl alcohol and characterized via X-ray diffraction and nitrogen adsorption. The adsorption and X-ray diffraction studies of the parent MCM-41 and the novel material are contrasted with a carbon derived from pure polyfurfuryl alcohol. The novel material has a high surface area, 850 m(2)/g, and a narrow pore size distribution centered at approximately 5 A. The novel material is unique when compared to traditional activated carbons or templated mesoporous carbons. The pores contained in the novel material are assembled using templating techniques and are half the size of pores contained in traditional carbons. Room temperature adsorption isotherms for the novel material and MCM-41 are presented for nitrogen, carbon dioxide, methane, and ethane. (C) 2007 Elsevier Inc. All rights reserved.

引用

页码：1 / 11

页数：11

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