Syntheses and crystal structures of novel silver(I) coordination polymers based on linear or tetrahedral coordination environments

被引：24

作者：

Uemura, Kazuhiro ^{[1
]}

机构：

[1] Yamaguchi Univ, Grad Sch Sci & Engn, Ube, Yamaguchi 7558611, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 07期

关键词：

silver(I); coordination polymer; crystal structure; amide; supramolecular assembly;

D O I：

10.1016/j.inoche.2008.03.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two coordination polymers containing Ag(I) atoms, (1Ag(3-pia)](PF6)}(n) (1) and {[Ag(3-pia)(2)](PF6)}(n) (2) (3-pia = N-pyridin-3-yl-isonicotinamide), have been synthesized using different solvents, and characterized by single X-ray analyses. In compound 1, Ag(l) atoms are linearly coordinated by two 3-pia ligands, resulting in one-dimensional chains. On the other hand, in compound 2, Ag(I) atoms are tetrahedrally coordinated by four 3-pia ligands, resulting in two-dimensional sheets. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：741 / 744

页数：4

共 37 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].