Syntheses and crystal structures of novel silver(I) coordination polymers based on linear or tetrahedral coordination environments

被引:24
作者
Uemura, Kazuhiro [1 ]
机构
[1] Yamaguchi Univ, Grad Sch Sci & Engn, Ube, Yamaguchi 7558611, Japan
关键词
silver(I); coordination polymer; crystal structure; amide; supramolecular assembly;
D O I
10.1016/j.inoche.2008.03.026
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two coordination polymers containing Ag(I) atoms, (1Ag(3-pia)](PF6)}(n) (1) and {[Ag(3-pia)(2)](PF6)}(n) (2) (3-pia = N-pyridin-3-yl-isonicotinamide), have been synthesized using different solvents, and characterized by single X-ray analyses. In compound 1, Ag(l) atoms are linearly coordinated by two 3-pia ligands, resulting in one-dimensional chains. On the other hand, in compound 2, Ag(I) atoms are tetrahedrally coordinated by four 3-pia ligands, resulting in two-dimensional sheets. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:741 / 744
页数:4
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