Syntheses and crystal structures of novel silver(I) coordination polymers based on linear or tetrahedral coordination environments

被引：24

作者：

Uemura, Kazuhiro ^{[1
]}

机构：

[1] Yamaguchi Univ, Grad Sch Sci & Engn, Ube, Yamaguchi 7558611, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 07期

关键词：

silver(I); coordination polymer; crystal structure; amide; supramolecular assembly;

D O I：

10.1016/j.inoche.2008.03.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two coordination polymers containing Ag(I) atoms, (1Ag(3-pia)](PF6)}(n) (1) and {[Ag(3-pia)(2)](PF6)}(n) (2) (3-pia = N-pyridin-3-yl-isonicotinamide), have been synthesized using different solvents, and characterized by single X-ray analyses. In compound 1, Ag(l) atoms are linearly coordinated by two 3-pia ligands, resulting in one-dimensional chains. On the other hand, in compound 2, Ag(I) atoms are tetrahedrally coordinated by four 3-pia ligands, resulting in two-dimensional sheets. (c) 2008 Elsevier B.V. All rights reserved.

引用

收藏

页码：741 / 744

页数：4

相关论文

共 37 条

[21] Metallosupramolecular isomerism: Switching from a cyclic to a chain assembly induced by benzo-fusion within a bridging ligand [J].

O'Keefe, Brendan J. ;

Steel, Peter J. .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (02) :247-249

[22] Crosslinking a palladium(II) polymer gives a laminated sheet structure [J].

Qin, ZQ ;

Jennings, MC ;

Puddephatt, RJ .

CHEMICAL COMMUNICATIONS, 2002, (04) :354-355

[23] Stacked molecular triangles: self-assembly using coordination chemistry and hydrogen bonding [J].

Qin, ZQ ;

Jennings, MC ;

Puddephatt, RJ .

CHEMICAL COMMUNICATIONS, 2001, (24) :2676-2677

[24] Tuning the coordination geometry of silver in bis(pyrazolyl)alkane complexes [J].

Reger, DL ;

Gardinier, JR ;

Smith, MD .

INORGANIC CHEMISTRY, 2004, 43 (13) :3825-3832

[25] The first metal complexes of 3,3′-bi-1,2,4-oxadiazole:: A curiously ignored ligand [J].

Richardson, Chris ;

Steel, Peter J. .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (08) :884-887

[26] Amide-to-amide hydrogen bonds in the presence of a pyridine functionality: Crystal structures of bis(pyridinecarboxamido)alkanes [J].

Sarkar, M ;

Biradha, K .

CRYSTAL GROWTH & DESIGN, 2006, 6 (01) :202-208

[27] Crystal engineering of metal-organic frameworks containing amide functionalities: Studies on network recognition, transformations, and exchange dynamics of guests and anions [J].

Sarkar, Madhushree ;

Biradha, Kumar .

CRYSTAL GROWTH & DESIGN, 2007, 7 (07) :1318-1331

[28] Copper(I) and silver(I) complexes of a new tetrahedrally-enforcing ligand containing two bipyridyl binding sites linked by a diphenyl disulfide bridge [J].

Thompson, AMWC ;

Blandford, I ;

Redfearn, H ;

Jeffery, JC ;

Ward, MD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (15) :2661-2665

[29] Structural flexibility of the hydrogen-free acceptor ligand octachloro-1,10-phenanthroline in its complexes with d(10) metal ions [J].

Titze, C ;

Kaim, W ;

Zalis, S .

INORGANIC CHEMISTRY, 1997, 36 (12) :2505-2510

[30] Pseudo-polyrotaxane and β-sheet layer-based three-dimensional coordination polymers constructed with silver salts and flexible pyridyl-type ligands [J].

Tong, ML ;

Wu, YM ;

Ru, J ;

Chen, XM ;

Chang, HC ;

Kitagawa, S .

INORGANIC CHEMISTRY, 2002, 41 (19) :4846-4848

← 1 2 3 4 →