Catalytic transfer hydrogenation and hydrogenolysis in ionic liquids with Pd/MgLa mixed oxide and Pd/MgAl hydrotalcite as recyclable catalysts

被引：7

作者：

Baan, Zoltan ^{[2
]}

Potor, Attila ^{[2
]}

Cwik, Agnieszka ^{[2
]}

Hell, Zoltan ^{[2
]}

Keglevich, Gyoergy ^{[2
]}

Finta, Zoltan ^{[1
]}

Hermecz, Istvan ^{[1
]}

机构：

[1] Chinoin Chem & Pharmaceut Works Ltd, Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1117 Budapest, Hungary

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 10期

关键词：

hydrotalcite; ionic liquids; palladium; transfer hydrogenation;

D O I：

10.1080/00397910801929523

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new Pd/MgLa mixed oxide and the known Pd/MgAl hydrotalcite catalysts were applied and recycled successfully in catalytic transfer hydrogenation reactions in ionic liquids. Some alpha,beta-unsaturated carboxylic acid derivatives were hydrogenated in excellent yields. The catalysts were recycled without significant loss of activity. Besides that, a number of halogenated aromatic compounds were dehalogenated under similar catalytic transfer conditions.

引用

页码：1601 / 1609

页数：9

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