Kinetics of CO oxidation on the surface of heterophase catalysts. Modeling by the Monte Carlo method

被引：10

作者：

Savchenko, VI

Efremova, NI

机构：

[1] Federal Scientific Center, Boreskov Institute of Catalysis

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1996年 / 57卷 / 01期

关键词：

CO oxidation; spillover; Monte Carlo method;

D O I：

10.1007/BF02076119

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Monte Carlo method has been used to simulate CO oxidation on a lattice consisting of various alternating patches: M1, where s(CO) > s(O-2) and M2, where s(CO) < s(O-2). The reaction is shown to proceed over all the surface at low temperature as COads spillover from M1 to M2 and backwards.

引用

页码：49 / 54

页数：6