Ligand electronic effects on rates of copper mediated atom transfer radical cyclisation and polymerisation

被引:34
作者
Clark, AJ [1 ]
Battle, GM
Heming, AM
Haddleton, DM
Bridge, A
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[2] Aventis Pharma Ltd, Dagenham RM10 7XS, Essex, England
关键词
radicals and radical reactions; cyclisations; copper and compounds; polymers;
D O I
10.1016/S0040-4039(01)00061-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The effect of different N-pentyl-2-pyridylmethanimine derivatives 2a-f upon the rate of copper(I) mediated atom transfer radical cyclisation (ATRC) of 5 and living atom transfer radical polymerisation (ATRP) of methylmethacrylate were investigated. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2003 / 2005
页数:3
相关论文
共 25 条