A bimetallic complex containing a cyclopentadienyl-annulated imidazol-2-ylidene

被引：58

作者：

Arduengo, AJ

Tapu, D

Marshall, WJ

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[2] DuPont Cent Res, Expt Stn, Wilmington, DE 19880 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 47期

关键词：

D O I：

10.1021/ja055565f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bimetallic carbene complex architecture that incorporates a cyclopentadienyl-annulated imidazol-2-ylidene moiety is characterized. The ligand architecture enables direct electronic interaction between the π- and σ-bonded metals. A preliminary example of aqueous Suzuki coupling employing a metallocene-fused imidazol-2-ylidene-derived catalyst is described. Copyright © 2005 American Chemical Society.

引用

页码：16400 / 16401

页数：2

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