Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives

被引：14

作者：

Dilman, AD

Arkhipov, DE

Korlyukov, AA

Ananikov, VP

Danilenko, VM

Tartakovsky, VA

机构：

[1] ND Zelinskii Inst Organ Chem, Moscow 119991, Russia

[2] Moscow Chem Lyceum, Moscow 109033, Russia

[3] AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 16期

基金：

俄罗斯基础研究基金会;

关键词：

organosilicon chemistry; tris(pentafluorophenyl)silyl derivatives; trichlorosilanes; structural studies;

D O I：

10.1016/j.jorganchem.2005.04.058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)(3)) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：3680 / 3689

页数：10

相关论文

共 48 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[2]

Bader R. F. W., 1990, ATOMS MOL QUANTUM TH, V22

[3] Rhodium catalyzed hydroformylation of β-pinene and camphene:: effect of phosphorous ligands and reaction conditions on diastereoselectivity [J].

Barros, HJV ;

Ospina, ML ;

Arguello, E ;

Rocha, WR ;

Gusevskaya, EV ;

dos Santos, EN .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 671 (1-2) :150-157

[4]

Bassindale AR, 1998, CHEM FUNCT, V2, P495, DOI 10.1002/0470857250.ch9

[5] SILYLATION OF ORGANIC HALIDES . A NEW METHOD OF FORMING CARBON-SILICON BOND [J].

BENKESER, RA ;

GAUL, JM ;

SMITH, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (13) :3666-&

[6] Mechanistic studies on the B(C6F5)3 catalyzed allylstannation of aromatic aldehydes with ortho donor substituents [J].

Blackwell, JM ;

Piers, WE ;

McDonald, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) :1295-1306

[7] STRUCTURE OF A 1-1 ADDUCT OF SILYL CHLORIDE AND DIMETHYL ETHER AT 100-K [J].

BLAKE, AJ ;

CRADOCK, S ;

EBSWORTH, EAV ;

FRANKLIN, KC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (01) :76-78

[8]

BOURY B, 2001, CHEM ORGANIC SILICON, V3, P565

[9] HYDROSILANE ADDITION OF PERFLUOROPHENYLSILANES TO SOME UNSATURATED SYSTEMS [J].

BRENNAN, T ;

GILMAN, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1969, 16 (01) :63-&

[10] REACTIVITY OF PENTACOORDINATE AND HEXACOORDINATE SILICON-COMPOUNDS AND THEIR ROLE AS REACTION INTERMEDIATES [J].

CHUIT, C ;

CORRIU, RJP ;

REYE, C ;

YOUNG, JC .

CHEMICAL REVIEWS, 1993, 93 (04) :1371-1448

← 1 2 3 4 5 →