Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives

被引：14

作者：

Dilman, AD

Arkhipov, DE

Korlyukov, AA

Ananikov, VP

Danilenko, VM

Tartakovsky, VA

机构：

[1] ND Zelinskii Inst Organ Chem, Moscow 119991, Russia

[2] Moscow Chem Lyceum, Moscow 109033, Russia

[3] AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 16期

基金：

俄罗斯基础研究基金会;

关键词：

organosilicon chemistry; tris(pentafluorophenyl)silyl derivatives; trichlorosilanes; structural studies;

D O I：

10.1016/j.jorganchem.2005.04.058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)(3)) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：3680 / 3689

页数：10

共 48 条

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