Hydrogen bonding directs the H2O2 oxidation of platinum(II) to a cis-dihydroxo platinum(IV) complex

被引：30

作者：

Taylor, Russell A. ^{[1
]}

Law, David J. ^{[2
]}

Sunley, Glenn J. ^{[2
]}

White, Andrew J. P. ^{[1
]}

Britovsek, George J. P. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 24期

关键词：

D O I：

10.1039/b803370f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of ligands with proximate hydrogen bonding substituents in the oxidation of platinum(II) dimethyl complexes with H2O2 leads to the exclusive formation of an unusual cis-dihydroxo platinum(IV) complex, which can dehydrate to form a trinuclear metalla-azacrown complex.

引用

页码：2800 / 2802

页数：3

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