The rhodium-catalyzed Pauson-Khand reaction

被引:141
作者
Kobayashi, T [1 ]
Koga, Y [1 ]
Narasaka, K [1 ]
机构
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
关键词
Pauson-Khand reaction; rhodium; catalytic reaction; cyclopentenone;
D O I
10.1016/S0022-328X(00)00835-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A rhodium carbonyl complex, [RhCl(CO)(2)](2), serves as a catalyst of the intra- and inter-molecular Pauson-Khand reaction. By the use of the rhodium catalyst, cyclopentenone derivatives are prepared from various 1,6- and 1,7-enynes under 1 arm of CO. Furthermore, this rhodium-catalyzed reaction is accelerated by reducing partial pressure of CO to less than 1 atm. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:73 / 87
页数:15
相关论文
共 59 条
  • [1] ADNO J, 1999, J AM CHEM SOC, V121, P7411
  • [2] Pauson-Khand reaction of activated olefins.
    Ahmar, M
    Antras, F
    Cazes, B
    [J]. TETRAHEDRON LETTERS, 1999, 40 (30) : 5503 - 5506
  • [3] Cyclopropylmethyl alkyl acetic acids and their bactericidal action toward B. Leprae. XIII
    Arvin, JA
    Adams, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1928, 50 : 1983 - 1985
  • [4] Thermal promotion of the cobalt catalyzed intramolecular Pauson-Khand reaction - An alternative experimental protocol for cyclopentenone synthesis
    Belanger, DB
    O'Mahony, DJR
    Livinghouse, T
    [J]. TETRAHEDRON LETTERS, 1998, 39 (42) : 7637 - 7640
  • [5] Hexacarbonyldicobalt-alkyne complexes as convenient Co2(CO)8 surrogates in the catalytic Pauson-Khand reaction
    Belanger, DB
    Livinghouse, T
    [J]. TETRAHEDRON LETTERS, 1998, 39 (42) : 7641 - 7644
  • [6] An intramolecular allenic [2+2+1]cycloaddition
    Brummond, KM
    Wan, HH
    Kent, JL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) : 6535 - 6545
  • [7] FISCHER CARBENE COMPLEXES FACILITATE THE INTRAMOLECULAR PAUSON-KHAND REACTION
    CAMPS, F
    MORETO, JM
    RICART, S
    VINAS, JM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (11): : 1470 - 1472
  • [8] PtCl2-catalyzed conversion of 1,6- and 1,7-enynes to 1-vinylcycloalkenes. Anomalous bond connection in skeletal reorganization of enynes
    Chatani, N
    Furukawa, N
    Sakurai, H
    Murai, S
    [J]. ORGANOMETALLICS, 1996, 15 (03) : 901 - 903
  • [9] HIGHLY SELECTIVE SKELETAL REORGANIZATION OF 1,6-ENYNE AND 1,7-ENYNE TO 1-VINYLCYCLOALKENES CATALYZED BY [RUCL2(CO)(3)](2)
    CHATANI, N
    MORIMOTO, T
    MUTO, T
    MURAI, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) : 6049 - 6050
  • [10] Chung YK, 1999, COORDIN CHEM REV, V188, P297