The rhodium-catalyzed Pauson-Khand reaction

被引:141
作者
Kobayashi, T [1 ]
Koga, Y [1 ]
Narasaka, K [1 ]
机构
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
关键词
Pauson-Khand reaction; rhodium; catalytic reaction; cyclopentenone;
D O I
10.1016/S0022-328X(00)00835-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A rhodium carbonyl complex, [RhCl(CO)(2)](2), serves as a catalyst of the intra- and inter-molecular Pauson-Khand reaction. By the use of the rhodium catalyst, cyclopentenone derivatives are prepared from various 1,6- and 1,7-enynes under 1 arm of CO. Furthermore, this rhodium-catalyzed reaction is accelerated by reducing partial pressure of CO to less than 1 atm. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:73 / 87
页数:15
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