Palladium-Catalyzed Oxidative Cross-Coupling Reaction of Arylboronic Acids with Diazoesters for Stereoselective Synthesis of (E)-α,β-Diarylacrylates

被引：70

作者：

Tsoi, Yuk-Tai

Zhou, Zhongyuan

Chan, Albert S. C.

Yu, Wing-Yiu ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, State Key Lab Chiosci, Kowloon, Hong Kong, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 20期

关键词：

ALPHA-DIAZOCARBONYL COMPOUNDS; CARBENE INSERTION; BIOLOGICAL EVALUATION; ARYLATION;

D O I：

10.1021/ol101796t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with alpha-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-alpha,beta-diarylacrylates were obtained in good yields and >20 1 E-to-Z selectivity

引用

页码：4506 / 4509

页数：4

共 36 条

[31] Palladium-Catalyzed Cross Coupling Reaction of Benzyl Bromides with Diazoesters for Stereoselective Synthesis of (E)-α,β-Diarylacrylates
Yu, Wing-Yiu
Tsoi, Yuk-Tai
Zhou, Zhongyuan
Chan, Albert S. C.
[J]. ORGANIC LETTERS, 2009, 11 (02) : 469 - 472
[32] Palladium-Catalyzed Decarboxylative Arylation of C-H Bonds by Aryl Acylperoxides
Yu, Wing-Yiu
Sit, Wing Nga
Zhou, Zhongyuan
Chan, Albert S. -C.
[J]. ORGANIC LETTERS, 2009, 11 (15) : 3174 - 3177
[33] Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence
Zhang, Zhenhua
Liu, Yiyang
Gong, Mingxing
Zhao, Xiaokun
Zhang, Yan
Wang, Jianbo
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (06) : 1139 - 1142
[34] Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids
Zhao, Xia
Jing, Jing
Lu, Kui
Zhang, Yan
Wang, Jianbo
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (10) : 1724 - 1726
[35] Toward the synthesis of caraphenol C: Substituent effect on the Nazarov cyclization of 2-arylchalcones
Zhu, Jun
Zhong, Chen
Lu, Hong-Fu
Li, Guang-Yu
Sun, Xun
[J]. SYNLETT, 2008, (03) : 458 - 462
[36] OVERLAP CONTROL OF CARBANIONOID REACTIONS .2. THE STEROCHEMISTRY OF THE PERKIN REACTION AND RELATED CONDENSATION REACTIONS
ZIMMERMAN, HE
AHRAMJIAN, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (09) : 2086 - 2091

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