Synthesis of poly(isobornyl acrylate) containing copolymers by atom transfer radical polymerization

被引：36

作者：

Dervaux, Bart ^{[1
]}

Van Camp, Wim ^{[1
]}

Van Renterghem, Lieven ^{[1
]}

Du Prez, Filip E. ^{[1
]}

机构：

[1] Univ Ghent, Dept Organ Chem, Polymer Chem Res Grp, B-9000 Ghent, Belgium

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 05期

关键词：

atom transfer radical polymerization (ATRP); block copolymers; block-like" copolymers; 1-ethoxyethyl acrylate; poly(isobornyl acrylate); stimuli-sensitive polymer;

D O I：

10.1002/pola.22505

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

For the first time, a detailed study of the atom transfer radical polymerization of isobornyl acrylate (iBA) is reported. On the basis of these results, well-defined PiBA-containing block copolymers were synthesized, focussing on the preparation of amphiphilic poly(acrylic acid) (PAA) containing block copolymers. The precursor monomers 1-ethoxyethyl acrylate (EEA) as well as tert-butyl acrylate have been used to synthesize the PAA-segments of the PiBA-b-PAA block copolymers. Finally, the synthesis of "block-like" copolymers of PiBA and PEEA via a one-pot procedure was investigated. By optimizing the copper and ligand concentration, and choosing the appropriate solvent, a controlled polymerization behaviour was obtained in all cases, as evidenced by a detailed kinetic analysis, GPC, NMR, and MALDI-TOF data. Thermogravimetric analysis confirmed the quantitative transformation of the precursor polymer PEEA to the corresponding PAA-containing copolymers. (C) 2008 Wiley Periodicals, Inc.

引用

页码：1649 / 1661

页数：13

共 47 条

[11] Synthesis and glass transition behavior of high molecular weight styrene/4-acetoxystyene and styrene/4-hydroxystyrene gradient copolymers made via nitroxide-mediated controlled radical polymerization [J].

Gray, MK ;

Zhou, HY ;

Nguyen, ST ;

Torkelson, JM .

MACROMOLECULES, 2004, 37 (15) :5586-5595

[12] Atom transfer polymerization of methyl methacrylate mediated by alkylpyridylmethanimine type ligands, copper(I) bromide, and alkyl halides in hydrocarbon solution [J].

Haddleton, DM ;

Crossman, MC ;

Dana, BH ;

Duncalf, DJ ;

Heming, AM ;

Kukulj, D ;

Shooter, AJ .

MACROMOLECULES, 1999, 32 (07) :2110-2119

[13] ENHANCED SOLUBILIZATION OF AROMATIC SOLUTES IN AQUEOUS-SOLUTIONS OF N-VINYLPYRROLIDONE STYRENE [J].

HAULBROOK, WR ;

FEERER, JL ;

HATTON, TA ;

TESTER, JW .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1993, 27 (13) :2783-2788

[14] RAFT polymerization of 1-ethoxyethyl acrylate: A novel route toward near-monodisperse poly(acrylic acid) and derived block copolymer structures [J].

Hoogenboom, R ;

Schubert, US ;

Van Camp, W ;

Du Prez, FE .

MACROMOLECULES, 2005, 38 (18) :7653-7659

[15] Controlled synthesis and characterization of high molecular weight methyl methacrylate/tert-butyl methacrylate diblock copolymers via ATRP [J].

Karanam, S ;

Goossens, H ;

Klumperman, B ;

Lemstra, P .

MACROMOLECULES, 2003, 36 (22) :8304-8311

[16] Chemical attachment of polystyrene-block-poly(methacrylic acid) micelles on a silicon nitride surface [J].

Karymov, MA ;

Prochazka, K ;

Mendenhall, JM ;

Martin, TJ ;

Munk, P ;

Webber, SE .

LANGMUIR, 1996, 12 (20) :4748-4753

[17] Polymer blend compatibilization by gradient copolymer addition during melt processing: Stabilization of dispersed phase to static coarsening [J].

Kim, J ;

Gray, MK ;

Zhou, HY ;

Nguyen, ST ;

Torkelson, JM .

MACROMOLECULES, 2005, 38 (04) :1037-1040

[18] Preparation of linear and star-shaped block copolymers by ATRP using simultaneous reverse and normal initiation process in bulk and miniemulsion [J].

Li, M ;

Jahed, NM ;

Min, K ;

Matyjaszewski, K .

MACROMOLECULES, 2004, 37 (07) :2434-2441

[19]

Liu YF, 2000, J APPL POLYM SCI, V76, P2093, DOI 10.1002/(SICI)1097-4628(20000628)76:14<2093::AID-APP13>3.0.CO

[20]

2-L

← 1 2 3 4 5 →