[mer,trans-(NN′N)RuCl2(NC5H5)]•C7H8 {NN′N=2,6-bis-[(dimethylamino)methyl]pyridine}

被引:3
作者
Back, S
Rheinwald, G
del Río, I
van Koten, G
Lang, H
机构
[1] Tech Univ Chemnitz, Fak Nat Wissensch, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany
[2] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain
[3] Univ Utrecht, Debye Inst Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词
D O I
10.1107/S1600536801014878
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, mer,trans-{2,6-bis[(dimethylamino)methyl]pyridine}dichloropyridineruthenium(II) toluene solvate, [RuCl2 (C11H19N3)(C5H5N)] . C7H8, has metal-ligand dimensions of Ru-N-py (NN'N) 1.962 (2) Angstrom, Ru-N(NN'N) 2.348 (3) Angstrom, Ru-N(NN'N) 2.251 (3) Angstrom, Ru-N-py 2.096 (2) Angstrom and Ru-Cl 2.3502 (7) or 2.3581 (7) Angstrom (py = pyridine, C5H5N). Angles are N-py-Ru-N(NN'N) 178.37 (9)degrees, (NN'N)N-Ru- N(NN'N) 160.57 (9)degrees and Cl-Ru-Cl 177.19 (3)degrees.
引用
收藏
页码:m444 / m445
页数:2
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