Reactivity of the binuclear ruthenium "Pincer' complex [{RuCl2(η3-NN′N)}2(μ-N2)] towards N-donor ligands.: The X-ray crystal structure of [RuCl2(η3-NN′N)(NCPh)] (NN′N=2,6-bis[(dimethylamino)methyl]pyridine)

被引：12

作者：

del Río, I

Back, S

Hannu, MS

Rheinwald, G

Lang, H

van Koten, G

机构：

[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

[2] Tech Univ Chemnitz, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

来源：

INORGANICA CHIMICA ACTA | 2000年 / 300卷 / 300-302期

关键词：

ruthenium complexes; pincer complexes; N-donor ligands; X-ray crystal structure;

D O I：

10.1016/S0020-1693(99)00610-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the binuclear, dinitrogen-bridged complex [{RuCl2(eta(3)-NN'N)}(2)(mu-N-2)] (3, NN'N = 2,6-bis[(dimethylamino)methyl]pyridine) with two equivalents of acetonitrile gives the mononuclear derivative mer, trans-[RuCl2(eta(3)-NN'N)(NCMe)] (4), while the use of an excess of this ligand leads to the formation of the monocationic isomers mer,trans-[RuCl(eta(3)-NN'N)(NCMe)(2)]Cl (5) and mer,cis-[RuCl(eta(3)-NN'N)(NCMe)(2)]Cl (6). In contrast, when 3 is treated with an excess of benzonitrile or pyridine, the only products formed are mer, trans-[RuCl2(eta(3)-NN'N)(NCPh)] (7) and mer, trans-[RuCl2(eta(3)-NN'N(py)] (8; py = pyridine), respectively. The X-ray structures of 7 and related reactions with other N-donor ligands are reported. (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：1094 / 1098

页数：5

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