A chemoselective aerobic oxidation of benzylic azides catalyzed by molybdenum xanthate in an aqueous medium

被引：36

作者：

Maddani, Mahagundappa ^{[1
]}

Prabhu, Kandikere Ramaiah ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 29-30期

关键词：

benzyl azides; molybdenum; redox reactions; aerobic oxidations; chemoselectivity; green chemistry;

D O I：

10.1016/j.tetlet.2008.05.047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild molybdenum-catalyzed, aerobic, chemoselective oxidation of benzylic azides to the corresponding aldehydes in an aqueous medium that tolerates a variety of functional groups including alcohols, esters, ketones, halides and olefins is described. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：4526 / 4530

页数：5

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