Controlled synthesis of new compounds using modulated elemental reactants

被引：68

作者：

Johnson, DC ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

[2] Univ Oregon, Inst Sci Mat, Eugene, OR 97403 USA

来源：

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 1998年 / 3卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S1359-0286(98)80082-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The design of modulated elemental reactants permits synthetic solid state chemists to control reaction intermediates. This has resulted in the synthesis of new binary and ternary compounds which are thermodynamically unstable relative to disproportionation into known compounds. The ability to control composition as a function of distance in one direction in these reactants permits the synthesis of crystalline superlattices.

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页码：159 / 167

页数：9

相关论文

共 34 条

[1] FIRST DIRECT OBSERVATION BY O-17 LIQUID NMR OF CO-CONDENSATION REACTIONS BETWEEN METHYL-SUBSTITUTED SILICON ALKOXIDES [J].

BABONNEAU, F ;

MAQUET, J ;

LIVAGE, J .

CHEMISTRY OF MATERIALS, 1995, 7 (06) :1050-1052

[2]

BECK H, 1981, GLASSY METALS, V1, P1

[3]

BROPHY JH, 1964, STRUCTURE PROPERTIES, V2, P98

[4] CALORIMETRIC STUDY OF AMORPHIZATION IN PLANAR, BINARY, MULTILAYER, THIN-FILM DIFFUSION COUPLES OF NI AND ZR [J].

COTTS, EJ ;

MENG, WJ ;

JOHNSON, WL .

PHYSICAL REVIEW LETTERS, 1986, 57 (18) :2295-2298

[5] SOLID-STATE CHEMISTRY - A REDISCOVERED CHEMICAL FRONTIER [J].

DISALVO, FJ .

SCIENCE, 1990, 247 (4943) :649-655

[6] DEPOSITION SYSTEM FOR THE SYNTHESIS OF MODULATED, ULTRATHIN-FILM COMPOSITES [J].

FISTER, L ;

LI, XM ;

MCCONNELL, J ;

NOVET, T ;

JOHNSON, DC .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1993, 11 (06) :3014-3019

[7]

FISTER L, 1992, J AM CHEM SOC, V114, P4369

[8] USE OF SUPERLATTICE STRUCTURE TO CONTROL REACTION-MECHANISM - KINETICS AND ENERGETICS OF NB5SE4 FORMATION [J].

FUKUTO, M ;

HORNBOSTEL, MD ;

JOHNSON, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9136-9140

[9] The effect of layer thickness and composition on the kinetics of solid state reactions in the niobium-selenium system studied using superlattice reactants [J].

Fukuto, M ;

Anderson, J ;

Hornbostel, MD ;

Johnson, DC ;

Huang, H ;

Kevan, SD .

JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 248 (1-2) :59-65

[10] INVESTIGATION OF PHASE-FORMATION SEQUENCE IN THE IRON-ALUMINUM PHASE-DIAGRAM USING SUPERLATTICE COMPOSITES AS REACTANTS [J].

GRANT, CA ;

JOHNSON, DC .

CHEMISTRY OF MATERIALS, 1994, 6 (07) :1067-1071

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