High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene

被引：107

作者：

Jiang, Jia-Xing

Laybourn, Andrea

Clowes, Rob

Khimyak, Yaroslav Z.

Bacsa, John

Higgins, Simon J.

Adams, Dave J.

Cooper, Andrew I. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

来源：

MACROMOLECULES | 2010年 / 43卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

NANOPOROUS POLYMERS; HYDROGEN STORAGE; NETWORKS;

D O I：

10.1021/ma101468r

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m(2)/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.

引用

页码：7577 / 7582

页数：6

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