Polythiophene-graft-styrene and polythiopene-graft-(styrene-graft-C60) copolymers

被引：54

作者：

Chen, Xiwen ^{[1
]}

Gholamkhass, Bobak ^{[1
]}

Han, Xu ^{[1
]}

Vamvounis, George ^{[1
]}

Holdcroft, Steven ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2007年 / 28卷 / 17期

关键词：

conjugated polymers; fullerenes; graft copolymers; polythiophenes; radical polymerization; self-assembly;

D O I：

10.1002/marc.200700292

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(3-hexylthiophene) was quantitatively brominated and subsequently used in the Suzuki cross-coupling with a boronic ester of a nitroxide to form a macroinitiator bearing a TEMPO group on each thienyl ring. This macroinitiator initiated the nitroxide-mediated radical polymerization of styrene and 4-chloromethylstyrene (CMS), and subsequently reacted with C-60 to yield soluble graft, rod-coil polymers. Films of the polymers display a bi-continuous phase structure as revealed by AFM. Similar polymers, in which only a fraction of the thienyl units boasted C-60-bearing side chains, displayed optical properties representative of extensive pi-delocalization. The potential application of this methodology for the synthesis of graft polymers for photovoltaic devices is discussed.

引用

页码：1792 / 1797

页数：6

共 34 条

[1] Grafting polymers onto C60 via an atom transfer reaction [J].

Audouin, F ;

Nunige, S ;

Nuffer, R ;

Mathis, C .

SYNTHETIC METALS, 2001, 121 (1-3) :1149-1150

[2] Well-defined fullerene-containing homopolymers and diblock copolymers with high fullerene content and their use for solution-phase and bulk organization [J].

Ball, ZT ;

Sivula, K ;

Fréchet, JMJ .

MACROMOLECULES, 2006, 39 (01) :70-72

[3] POLYMER-POLYMER PHASE-BEHAVIOR [J].

BATES, FS .

SCIENCE, 1991, 251 (4996) :898-905

[4] Highly efficient blue electroluminescence from poly(phenylene ethynylene) via energy transfer from a hole-transport matrix [J].

Breen, CA ;

Tischler, JR ;

Bulovic, V ;

Swager, TM .

ADVANCED MATERIALS, 2005, 17 (16) :1981-+

[5] Polarized photoluminescence from poly(p-phenylene-ethynylene) via a block copolymer nanotemplate [J].

Breen, CA ;

Deng, T ;

Breiner, T ;

Thomas, EL ;

Swager, TM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) :9942-9943

[6] Supramolecular self-assembly and opto-electronic properties of semiconducting block copolymers [J].

de Boer, B ;

Stalmach, U ;

van Hutten, PF ;

Melzer, C ;

Krasnikov, VV ;

Hadziioannou, G .

POLYMER, 2001, 42 (21) :9097-9109

[7]

Ding JF, 2002, ADV FUNCT MATER, V12, P389, DOI 10.1002/1616-3028(20020517)12:5<389::AID-ADFM389>3.0.CO

[8]

2-5

[9] Morphologically controlled proton-conducting membranes using graft polymers possessing block copolymer graft chains [J].

Ding, JF ;

Tang, QY ;

Holdcroft, S .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2002, 55 (6-7) :461-466

[10] Enhanced conductivity in morphologically controlled proton exchange membranes: Synthesis of macromonomers by SFRP and their incorporation into graft polymers [J].

Ding, JF ;

Chuy, C ;

Holdcroft, S .

MACROMOLECULES, 2002, 35 (04) :1348-1355

← 1 2 3 4 →