Ferrocenic polyphosphines and polythioethers: synthesis, reactivity and structure

被引：26

作者：

Broussier, R ^{[1
]}

Ninoreille, S ^{[1
]}

Bourdon, C ^{[1
]}

Blacque, O ^{[1
]}

Ninoreille, C ^{[1
]}

Kubicki, MM ^{[1
]}

Gautheron, B ^{[1
]}

机构：

[1] CNRS, UMR 5632, Lab Synthese & Electrosynth Organomet, F-21004 Dijon, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 561卷 / 1-2期

关键词：

cyclopentadienyl; ferrocene; phosphine; thioether; group 6 metal carbonyl;

D O I：

10.1016/S0022-328X(98)00551-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ferrocenic polyphosphines [C5Me3-1,2-(PPh2)(2)](C5H5)Fe 2, [C5Me3-1,2-(PPh2)(2)](2),Fe 3, [C5Me3-1,2-(PPh2)(2)][C5Me4(PPh2)]Fe 4 and polythioethers [C5Me3-1,2-(SCH2CH2CH3)2](2)Fe 6 and [C5Me3-1,2-(SCH2CH2CH3)(2)](C5H5)Fe 7 have been prepared. The X-ray crystal structures of 3 and 6 have been determined. Some aspects of the reactivity of compounds 2, 3 and 4 are reported (P(III)-->P(V) transformation, chelating properties) as well as the X-ray structure of [C5Me3-1,2(PPh2)(2)W(CO)(4)](C5H5)Fe 15. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：85 / 96

页数：12

共 26 条

[1] PREPARATION AND CRYSTAL-STRUCTURES OF SYN-[(MU-SPH)FE(CO)3]2, (C5H4SPH)2FE, (C5H5)FE(C5H4SPH), AND (C5H4SPH)FE(C5H4PPH2)
ADELEKE, JA
CHEN, YW
LIU, LK
[J]. ORGANOMETALLICS, 1992, 11 (07) : 2543 - 2550
[2] DIAMAGNETIC REVERSIBLE PARAMAGNETIC EQUILIBRIA IN SOLUTIONS OF BIS(DIALKYLPHOSPHINO)ETHANE COMPLEXES OF IRON
BAKER, MV
FIELD, LD
HAMBLEY, TW
[J]. INORGANIC CHEMISTRY, 1988, 27 (16) : 2872 - 2876
[3] SYNTHESIS, SPECTROSCOPY, BONDING AND STRUCTURE IN PHOSPHIDO-BRIDGED BIMETALLICS DERIVED FROM BENT METALLOCENES OF MOLYBDENUM AND TUNGSTEN AND FROM GROUP-6 METAL-CARBONYLS
BARRE, C
BOUDOT, P
KUBICKI, MM
MOISE, C
[J]. INORGANIC CHEMISTRY, 1995, 34 (01) : 284 - 291
[4] TRANSITION-METAL COMPLEXES OF 7-MEMBERED RING SYSTEMS .4. PROTON RESONANCE SPECTRA OF CYCLOHEPTATRIENE COMPLEXES OF GROUP VI METALS
BENNETT, MA
WILKINSON, G
PRATT, L
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (MAY): : 2037 - +
[5] Broussier R, 1996, B SOC CHIM FR, V133, P843
[6] Propylthiotetramethylcyclopentadienyl complexes of iron, titanium and zirconium. Structural characterization of [eta(5)-C5Me4SCH2CH2CH3](2)TiCl2
Broussier, R
Bourdon, C
Blacque, O
Vallat, A
Kubicki, MM
Gautheron, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 538 (1-2) : 83 - 90
[7] Cyclopentadiene with two coordinating sites: 1,5-bis(diphenylphosphino)-2,3,4-trimethylcyclopenta-1,3-diene
Broussier, R
Ninoreille, S
Legrand, C
Gautheron, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 532 (1-2) : 55 - 60
[8] BUTLER IR, 1993, POLYHEDRON, V12, P1091
[9] EFFECTS OF SUBSTITUTIONS ON CYCLOPENTADIENYL RINGS IN COMPLEXES WITH MOLYBDENUM MERCURY BONDS - MO-95 AND HG-199 NMR-STUDIES
CANO, M
CAMPO, JA
PINILLA, E
MONGE, A
PICHON, R
SALAUN, JY
LHARIDON, P
SZYMONIAK, J
KUBICKI, MM
[J]. INORGANICA CHIMICA ACTA, 1995, 228 (02) : 251 - 254
[10] HETEROPOLYMETALLIC COMPLEXES OF 1,1'-BIS(DIPHENYLPHOSPHINO) FERROCENE (DPPF) .2. CRYSTAL-STRUCTURE OF DPPF AND NICL2(DPPF)
CASELLATO, U
AJO, D
VALLE, G
CORAIN, B
LONGATO, B
GRAZIANI, R
[J]. JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1988, 18 (05): : 583 - 590

← 1 2 3 →