Environmental synthesis of silver nanoparticles using hydroxypropyl starch and their characterization

被引：136

作者：

El-Rafie, M. H. ^{[2
]}

El-Naggar, M. E. ^{[1
,2
]}

Ramadan, M. A. ^{[2
]}

Fouda, Moustafa M. G. ^{[1
,2
]}

Al-Deyab, Salem S. ^{[3
]}

Hebeish, A. ^{[2
]}

机构：

[1] King Saud Univ, Strateg Ctr Diabet Res, Nanotechnol Dept, Riyadh 11411, Saudi Arabia

[2] Natl Res Ctr, Text Res Div, Giza 12522, Egypt

[3] King Saud Univ, Coll Sci, Dept Chem, Petrochem Res Chair, Riyadh 11451, Saudi Arabia

来源：

CARBOHYDRATE POLYMERS | 2011年 / 86卷 / 02期

关键词：

Green chemistry; Nanomaterials; Chemical reduction; Silver nanoparticles; AG; REDUCTION; GOLD;

D O I：

10.1016/j.carbpol.2011.04.088

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Silver nanoparticles (AgNPs) were synthesized in an alkaline aqueous solution of silver nitrate (AgNO3)/hydroxypropyl starch (HPS) using chemical reduction method. HPS is water soluble/biocompatible starch derivative which play a dual rule as reducing agent for silver ions and as stabilizing agent too for the formed AgNPs. The influences of the reaction parameters, such as the concentrations of HPS and AgNO3. pH, temperature, and duration of the reaction medium on the size and agglomeration of the formed AgNPs were studied. The formation of AgNPs has been confirmed with ultraviolet-visible spectra and transmission electron microscopy (TEM) images. The diameter range of well stabilized AgNPs solution with a concentration of 500 ppm of a diameter of 6-8 nm was obtained. The obtained AgNPs remain without aggregation for more than six months. The advantage of this methodology is that it is possible to prepare AgNPs without any organic solvents or other reducing agents. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：630 / 635

页数：6

共 27 条

[1] Semiconductor clusters, nanocrystals, and quantum dots [J].

Alivisatos, AP .

SCIENCE, 1996, 271 (5251) :933-937

[2]

ELNAGGAR ME, 2008, SYNTHESIS CHARACTERI

[3] Effect of amine groups in the synthesis of Ag nanoparticles using aminosilanes [J].

Frattini, A ;

Pellegri, N ;

Nicastro, D ;

de Sanctis, O .

MATERIALS CHEMISTRY AND PHYSICS, 2005, 94 (01) :148-152

[4] Preparation and formation mechanisms of uniform metallic particles in homogeneous solutions [J].

Goia, DV .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (04) :451-458

[5]

GUANG Y, 2007, COLLOID SURFACE B, V59, P171

[6]

Huang H., 2008, CARBOHYD POLYM, V27, P309

[7] Synthesis of chitosan-stabilized gold nanoparticles in the absence/presence of tripolyphosphate [J].

Huang, HZ ;

Yang, XR .

BIOMACROMOLECULES, 2004, 5 (06) :2340-2346

[8] Silver Nanoparticles in Therapeutics: Development of an Antimicrobial Gel Formulation for Topical Use [J].

Jain, Jaya ;

Arora, Sumit ;

Rajwade, Jyutika M. ;

Omray, Pratibha ;

Khandelwal, Sanjeev ;

Paknikar, Kishore M. .

MOLECULAR PHARMACEUTICS, 2009, 6 (05) :1388-1401

[9] REDUCTION AND AGGREGATION OF SILVER IONS IN AQUEOUS GELATIN SOLUTIONS [J].

KAPOOR, S ;

LAWLESS, D ;

KENNEPOHL, P ;

MEISEL, D ;

SERPONE, N .

LANGMUIR, 1994, 10 (09) :3018-3022

[10] Water based simple synthesis of re-dispersible silver nano-particles [J].

Khanna, P. K. ;

Singh, Narendra ;

Kulkarni, Deepti ;

Deshmukh, S. ;

Charan, Shobhit ;

Adhyapak, P. V. .

MATERIALS LETTERS, 2007, 61 (16) :3366-3370

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