Micropatterning of ZnO nanoarrays by forced hydrolysis of anhydrous zinc acetate

被引:45
作者
Hu, Xiulan [1 ]
Masuda, Yoshitake [1 ]
Ohji, Tatsuki [1 ]
Kato, Kazumi [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Moriyama Ku, Nagoya, Aichi 4638560, Japan
关键词
D O I
10.1021/la8006348
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Micropatterns of ZnO nanoarrays were simply and successfully fabricated in an aqueous solution without any high-temperature treatment and/or expensive catalyst. In situ forced hydrolysis of patterned anhydrous zinc acetate, derived by ultraviolet irradiation with a photomask, resulted in heterogeneous nucleation and growth to form ZnO nanoarrays. Micropatterns of ZnO nanoarrays were characterized by FE-SEM and XRD. ZnO nanoarrays were well site-selectively deposited on anhydrous zinc acetate coated regions at 88 degrees C. HR-TEM clarified the formation mechanism in which anhydrous zinc acetate showed a tendency of forced hydrolyzation to ZnO nanocrystals at the initial stage in the reaction solution.
引用
收藏
页码:7614 / 7617
页数:4
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