Template-directed construction of conformational supramolecular isomers for bilayer porous metal-organic frameworks with distinct gas sorption behaviors

被引：58

作者：

Chen, Min ^{[1
]}

Zhao, Hui ^{[1
]}

Liu, Chun-Sen ^{[1
]}

Wang, Xi ^{[1
,2
]}

Shi, Heng-Zhen ^{[1
]}

Du, Miao ^{[1
,2
]}

机构：

[1] Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Peoples R China

[2] Tianjin Normal Univ, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin Key Lab Struct & Performance Funct Mol, Coll Chem, Tianjin 300387, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 27期

基金：

中国国家自然科学基金;

关键词：

SLOW MAGNETIC-RELAXATION; COORDINATION POLYMER; CO2; CAPTURE; ADSORPTION; SEPARATION; BINDING; POLYMORPHISM; ADJUSTMENT; CATALYSIS; LIGAND;

D O I：

10.1039/c5cc00018a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A pair of supramolecular isomers of Co(II)-based metal-organic frameworks can be directionally constructed in virtue of solvent templates, which show diverse bilayer networks and lattice packing with the same Co-3 SBUs and organic linkers. The two porous materials show distinct gas sorption behaviors at different temperatures, especially their CO2 sorption selectivity.

引用

收藏

页码：6014 / 6017

页数：4

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