Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent

被引：220

作者：

Ishiyama, T ^{[1
]}

Nobuta, Y

Hartwig, JF

Miyaura, N

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 23期

关键词：

D O I：

10.1039/b311103b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic C-H borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane was catalyzed by an iridium complex generated from 1/2[Ir(OMe)(COD)](2) and 4,4'-di-tert-butyl-2,2'-bipyridine at room temperature in hexane and afforded the corresponding aryl- and heteroarylboronates in high yields with excellent regioselectivities.

引用

页码：2924 / 2925

页数：2

共 35 条

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