Influence of cyclic organosilicon precursors on the corrosion of aluminium coated sheet by atmospheric pressure dielectric barrier discharge

被引:10
作者
Boscher, Nicolas D. [1 ]
Choquet, Patrick [1 ]
Duday, David [1 ]
Verdier, Stephane [2 ]
机构
[1] Ctr Rech Publ Gabriel Lippmann, Dept Sci & Anal Mat, L-4422 Belvaux, Luxembourg
[2] Foil Innovat Ctr, L-4422 Belvaux, Luxembourg
关键词
Octamethylcyclotetrasiloxane (OMCTS); Decamethylcyclopentasiloxane (DMCPS); AP-DBD; Corrosion; Aluminium; THIN-FILM DEPOSITION; 2P CORE-LEVEL; ELECTROCHEMICAL-BEHAVIOR; MECHANICAL-PROPERTIES; SILOXANE COATINGS; PLASMA DEPOSITION; CONSTANT; LAYERS; SPECTROSCOPY; POLYESTER;
D O I
10.1016/j.surfcoat.2011.05.043
中图分类号
TB3 [工程材料学];
学科分类号
082905 [生物质能源与材料];
摘要
Atmospheric pressure dielectric barrier discharge depositions on aluminium of octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane were investigated. Scanning Electron Microscopy and Transmission Electron Microscopy revealed the formation of dense and defect free layers while Fourier Transform Infrared Spectroscopy and X-ray Photoelectron Spectroscopy analyses indicated the formation of highly cross-linked siloxane layers. The corrosion protection afforded by such films was investigated by electrochemical techniques and relationships between the deposition parameters, film chemistry and electrochemical properties of these films are reported. The corrosion performances of films grown from the two cyclic siloxane precursors were shown to be significantly higher than the ones achieved by the films grown from hexamethyldisiloxane in previous work. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:5350 / 5357
页数:8
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