Direction of unusual mixed-ligand metal-organic frameworks: a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network

被引:227
作者
Du, M [1 ]
Jiang, XJ [1 ]
Zhao, XJ [1 ]
机构
[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China
关键词
D O I
10.1039/b509875k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of Cu-II or Cd-II acetate with mixed ligands terephthatic (tp) and 3,5-bis(4-pyridyl)4-amino-1,2,4-triazole (bpt) under the same conditions affords two unusual metal-organic frameworks, in which I represents a new type of polythreaded supramolecular architecture consisting of distinct 1-D, and 2-D coordination polymers within one crystal, however, 2 has an interpenetrating porous network with two similar laterally interlocking 2-D (4,4) layers.
引用
收藏
页码:5521 / 5523
页数:3
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