Inorganic-organic hybrids derived from oxovanadium sulfate motifs:: synthesis and characterization of [VIVO( μ3-SO4)(2,2′-bpy)]∞

被引：48

作者：

Khan, MI ^{[1
]}

Cevik, S

Doedens, RJ

机构：

[1] IIT, Dept Biol Chem & Phys Sci, Chicago, IL 60616 USA

[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 19期

关键词：

D O I：

10.1039/b106866k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermal reaction of V2O5, V2O3, 2,2'-bpy and Na2SO4 in dilute sulfuric acid yields a novel hybrid, [(VO)-O-IV(mu (3)-SO4)(2,2'-bpy)]proportional to, which demonstrates the potential of constructing a new class of robust composite solids composed of a {V/O/SO4}-based framework decorated with organic functionalities by combining appropriate vanadyl sulfate motifs with a variety of organic ligands.

引用

页码：1930 / 1931

页数：2

共 26 条

[21] ORGANICALLY TEMPLATED OPEN-FRAMEWORK VANADIUM PHOSPHATES - HYDROTHERMAL SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF H3N(CH2)3NH3[(VO)3(OH)2(H2O)2(PO4)2] [J].