Influence of hydroperoxides on the enantioselectivity of metal-catalyzed asymmetric Baeyer-Villiger oxidation and epoxidation with chiral ligands

被引：56

作者：

Bolm, C

Beckmann, O

Kühn, T

Palazzi, C

Adam, W

Rao, PB

Saha-Möller, CR

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 17期

关键词：

D O I：

10.1016/S0957-4166(01)00417-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral hydroperoxides have a significant influence on the enantioselectivity of the metal-catalyzed asymmetric Baeyer-Villiger oxidation of cyclic ketones and the epoxidation of allylic alcohols, when chiral ligands are employed. If both the ligand and the hydroperoxide are enantiopure. the ligand determines the formation of the preferred product enantiomer in both reactions. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2441 / 2446

页数：6