Fluorous metal-organic frameworks for high-density gas adsorption

被引：317

作者：

Yang, Chi ^{[1
]}

Wang, Xiaoping ^{[1
]}

Omary, Mohammad A. ^{[1
]}

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 50期

关键词：

D O I：

10.1021/ja0775265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fluorous metal-organic framework, FMOF-1, is obtained by reaction of Ag(I) with 3,5-bis(trifluoromethyl)-1,2,4-triazolate, giving rise to a neutral, hydrogen-free, extended 3D nanotubular porous framework consisting of tetranuclear clusters [Ag(4)TZ(6)] connected by three-coordinate Ag(I) centers. The fluoro-lined channels and cavities of the framework show hysteretic adsorption of H-2 with a volumetric capacity of 41 kg/m(3) at 77 K and 64 bar. The framework also exhibits very high adsorptions for O-2 and N-2 with volumetric uptake of similar to 550 and 400 kg/m(3) at 77 K even at very low pressures (< 10(-2) bar).

引用

页码：15454 / +

页数：3

共 43 条

[41] Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties [J].