Cobalt, zinc, and nickel complexes of a diatopic heteroscorpionate ligand: Building blocks for coordination polymers

被引:33
作者
Santillan, Guillermo A. [1 ]
Carrano, Carl J. [1 ]
机构
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
关键词
D O I
10.1021/ic701718b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New binuclear complexes of Co(II), Zn(II), and Ni(II) derived from a diatopic heteroscorpionate ligand, (4-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L4c), have been synthesized and characterized by X-ray diffraction, ESI-MS, IR, UV-vis spectroscopy, and magnetic susceptibility. These building blocks have been subsequently used for the construction of higher order metallosupramolecular architectures.
引用
收藏
页码:930 / 939
页数:10
相关论文
共 38 条
[1]   Self-assembly and host-guest chemistry of big metallosupramolecular M4L4 tetrahedra [J].
Albrecht, Markus ;
Janser, Ingo ;
Burk, Simon ;
Weis, Patrick .
DALTON TRANSACTIONS, 2006, (23) :2875-2880
[2]  
Calhorda MJ, 2006, DALTON T, P4104, DOI 10.1039/b605034d
[3]  
Caneschi A, 2001, ANGEW CHEM INT EDIT, V40, P1760, DOI 10.1002/1521-3773(20010504)40:9<1760::AID-ANIE17600>3.0.CO
[4]  
2-U
[5]   Evidence for single-chain magnet behavior in a MnIII-NiII chain designed with high spin magnetic units:: A route to high temperature metastable magnets [J].
Clérac, R ;
Miyasaka, H ;
Yamashita, M ;
Coulon, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) :12837-12844
[6]   Hydrogen storage in metal-organic frameworks [J].
Collins, David J. ;
Zhou, Hong-Cai .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3154-3160
[7]   Supramolecular arrays based on dimetal building units [J].
Cotton, FA ;
Lin, C ;
Murillo, CA .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (10) :759-771
[8]   Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].
Dinca, Mircea ;
Dailly, Anne ;
Liu, Yun ;
Brown, Craig M. ;
Neumann, Dan. A. ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16876-16883
[9]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[10]  
Evans AE, 2000, MED PEDIATR ONCOL, V35, P511, DOI 10.1002/1096-911X(20001201)35:6<511::AID-MPO1>3.3.CO