Cobalt, zinc, and nickel complexes of a diatopic heteroscorpionate ligand: Building blocks for coordination polymers

被引:33
作者
Santillan, Guillermo A. [1 ]
Carrano, Carl J. [1 ]
机构
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
关键词
D O I
10.1021/ic701718b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New binuclear complexes of Co(II), Zn(II), and Ni(II) derived from a diatopic heteroscorpionate ligand, (4-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L4c), have been synthesized and characterized by X-ray diffraction, ESI-MS, IR, UV-vis spectroscopy, and magnetic susceptibility. These building blocks have been subsequently used for the construction of higher order metallosupramolecular architectures.
引用
收藏
页码:930 / 939
页数:10
相关论文
共 38 条
[11]  
2-A
[12]  
Holliday BJ, 2001, ANGEW CHEM INT EDIT, V40, P2022, DOI 10.1002/1521-3773(20010601)40:11<2022::AID-ANIE2022>3.0.CO
[13]  
2-D
[14]   Molecular tectonics: From simple tectons to complex molecular networks [J].
Hosseini, MW .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :313-323
[15]   Antiferromagnetic interaction achieved by a 3-D supramolecular CuII complex with pyrazino-fused TTF as the ligand, [CuCl2(BP-TTF)] [J].
Ichikawa, Shun ;
Kimura, Shinya ;
Mori, Hatsumi ;
Yoshida, Gosuke ;
Tajima, Hiroyuki .
INORGANIC CHEMISTRY, 2006, 45 (19) :7575-7577
[16]   Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].
Leininger, S ;
Olenyuk, B ;
Stang, PJ .
CHEMICAL REVIEWS, 2000, 100 (03) :853-907
[17]   Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: A stepwise ion pair guest dissociation mechanism [J].
Leung, Dennis H. ;
Bergman, Robert G. ;
Raymond, Kenneth N. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9781-9797
[18]   Hydrogen storage in metal-organic frameworks [J].
Lin, Xiang ;
Jia, Junhua ;
Hubberstey, Peter ;
Schroeder, Martin ;
Champness, Neil R. .
CRYSTENGCOMM, 2007, 9 (06) :438-448
[19]   Formation of artificial receptors by metal-templated self-assembly [J].
Linton, B ;
Hamilton, AD .
CHEMICAL REVIEWS, 1997, 97 (05) :1669-1680
[20]   Assembly of metal-organic frameworks (MOFs) based on indium-trimer building blocks: A porous MOF with soc topology and high hydrogen storage [J].
Liu, Yunling ;
Eubank, Jarrod F. ;
Cairns, Amy J. ;
Eckert, Juergen ;
Kravtsov, Victor Ch. ;
Luebke, Ryan ;
Eddaoudi, Mohamed .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (18) :3278-3283