Dual ion-beam-assisted deposition as a method to obtain low loading-high performance electrodes for PEMFCs

被引:18
作者
Gullá, AF
Saha, MS
Allen, RJ
Mukerjee, S
机构
[1] Nora N Amer Inc, ETEK Div, Somerset, NJ 08873 USA
[2] Northeastern Univ, Dept Chem & Chem Biol, Boston, MA 02115 USA
关键词
D O I
10.1149/1.2008887
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ultralow loading noble metal (Pt) electrodes, for proton exchange membrane fuel cells (PEMFCs ), were prepared via dual ion-beam assisted deposition of pure Pt metal particles directly onto the surface of a noncatalyzed E-TEK gas diffusion layer. Activity enhancement, based on normalization with electrochemical surface area and mass activity is reported relative to a commercial gas diffusion electrode containing carbon-supported Pt electrocatalysts. The enhanced performance was primarily dictated by the cathodic oxygen reduction reaction. Based on the morphological differences, which enable such enhanced activities and the mass manufacturability of this electrode system, we report a significant new development in terms of materials for PEMFC application. (c) 2005 The Electrochemical Society.
引用
收藏
页码:A504 / A508
页数:5
相关论文
共 48 条
[1]  
ALLEN RJ, 2000, Patent No. 6077621
[2]   Pt submonolayers on Ru nanoparticles - A novel low Pt loading, high CO tolerance fuel cell electrocatalyst [J].
Brankovic, SR ;
Wang, JX ;
Adzic, RR .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (12) :A217-A220
[3]  
Cavalca CA, 2001, US Pat, Patent No. 6300000
[4]  
CHOI KH, 2000, HWAHAK KONGHAK, V38, P1
[5]   Electrocatalytic reduction of dioxygen at platinum particles dispersed in a polyaniline film [J].
Coutanceau, C ;
Croissant, MJ ;
Napporn, T ;
Lamy, C .
ELECTROCHIMICA ACTA, 2000, 46 (04) :579-588
[6]  
DEBE MK, 1999, Patent No. 97948851
[7]  
DEBE MK, 1999, Patent No. 97948627
[8]  
DEBE MK, 1999, Patent No. 5879827
[9]  
DEBE MK, 1999, Patent No. 97948599
[10]  
FERNANDES MG, 1996, J MATER RES, V5, P98